When light
radiation (UV, VIS, IR, THz) is applied to a
thin pyroelectric crystal (<40µm) its
temperature increases by fractions of a
degree centigrade. Turning on the radiation
an electrical charge is generated by
heating, turning off the light the crystal
cools down and an opposite charge is
generated. These very small electrical
charges are generally converted within the
detector housing to convenient signal
voltages by use of extremely low noise and
low leakage Field Effect Transistors (JFET)
or CMOS operational amplifiers (OpAmp). It
is very important to remember that only
modulated radiation creates a signal,
therefore either pulsed or mechanically
chopped IR sources are used and unmodulated
disturbing background radiation is filtered
out.
In what
wavelength range do pyroelectric detectors
operate?
As the thermal
effect of the incoming radiation is used to
produce the electrical detector response,
electromagnetic radiation from deep UV
(100nm) over the visible range to the far
infrared up to the THz range (1000µm) can be
detected, as long as the pyroelectric
crystal is covered with a suitable
absorption layer. InfraTec use two different
coating technologies for black absorbing
layers. The polymer black coating is used
for most detectors and offers extremely
stable long term absorption from UV up to
100µm IR even for high modulation
frequencies (max 4kHz). A special metal
black coating is used especially for
spectrometer detectors and is characterized
by an extremely flat and high absorbance but
is sensitive for operating temperatures
>60°C, high radiation power as well as
strong vibrations.
What are
pyroelectric detectors used for?
A pyroelectric
detector can be used very exactly and with
long term stability to measure IR radiation.
As the pyroelectric element only reacts to a
change of the IR radiation the detector must
always be used with a modulated
(mechanically chopped or electrically
pulsed) radiation source. Since pyroelectric
detectors operate on a thermal phenomenon
they have a very broad spectral response -
between 100 nm to over 1000 µm without any
cooling like semiconductor detectors. Most
common applications are motion detection,
NDIR gas analysis, flame detection with
spectroscopy and radiometry also possible.
Even if pyroelectric detectors are thermal
detectors they are able to measure signals
up to some kHz with high performance. Short
pulses can be detected down to some µs
(microseconds) but with considerable loss of
signal-to-noise.
What is a NDIR
gas analyzer typically made of?
A large number
of materials absorb infrared (IR) radiation
due to intramolecular vibrations. For any
specific material the strength of absorption
varies with the wavelength of the infrared
radiation. This principle is often used in
gas analysis. An NDIR (Non Dispersive IR)
gas analyzer contains an electrically or
mechanically modulated IR source, a gas
chamber with the gas of interest and a
pyroelectric detector. Normally a standard
narrow bandpass filter (NBP) that matches
the absorption wavelength of the target gas
is integrated in the detector cap and
simplified the gas sensor design.
How does a flame
sensor work?
The pyroelectric detector of a flame sensor is
detecting the typical spectral radiation of
burning organic (hyrdocarbon) materials
(wood, natural gas, petrol, plastics). Two
criteria are used to distinguish a flame
from the sun or any other light source. 1) A
typical fire is "self-modulated" around
10Hz by flickering. 2) A hydrocarbon flame
is producing the combustion gases of carbon
CO and CO2. The emission bands of CO2 and CO
in the infrared range are between 4.0 and
4.8µm. A built-in IR bandpass is passing
only the emission bands of both CO2 and CO
to the pyroelectric element. Computing both
flicker frequency and spectral information
4.0-4.8µm will suppress false alarms
effectively.
Is it possible
to use pyroelectric detectors which contain
neither a JFET nor an OpAmp thus only the
pyroelectric element in gas analysis and
flame detection?
The charges
created in the pyroelectric crystal are very
small and need to be amplified by
preamplifiers with very high input
impedances (up to some 10 GOhm). At ambient
conditions (for example 60% relative
humidity and 23°C) such circuitry cannot be
operated without disturbances. At least the
high impedance part of the circuitry should
be within the hermetically sealed detector
housing. We therefore recommend using
detectors with integrated JFET or OpAmp for
gas analysis and flame detection.
Is it useful to
cool down pyroelectric detectors for example
by using a Peltier device to improve the
signal-to-noise-ratio?
No. Pyroelectric detectors unlike PbS or PbSe
detectors do not need any cooling even for
the detection of longwave radiation in the
range of 8-14 µm. But operating temperatures
of over 50° C do however increase the
detector noise, as the integrated amplifier
components exhibit larger leakage currents
at higher temperatures. It is noteworthy
that CMOS OpAmps react much less as JFET's,
as the gate leakage current of a JFET
increases exponentially with temperature.
For applications with operating temperatures
above 60°C always consider the use of
detectors with CMOS operational amplifiers.
Is it useful to
heat pyroelectric detectors to improve the
signal-to-noise-ratio?
No! Pyroelectric
detectors for FTIR spectrometers are
sometimes operated at higher temperatures of
about 50°C because here a special pyroelectric crystal (DTGS) is used instead
of LiTaO3 used by InfraTec. This DTGS
crystal material has a Curie temperature of
about 59°C, LiTaO3 shows 620°C. Near to the
Curie temperature the pyroelectric
coefficient and resulting signal voltages
are growing remarkably but with the side
effect of a very high temperature
coefficient. A visible signal increase by
warming the LiTaO3 detector is not possible
due to the very high Curie temperature but
otherwise the temperature coefficient of
LiTaO3 is extremely low. Heating of LiTaO3
detectors (40 ... 60°C) is only common for
gas analyzers to avoid a condensation of wet
gases or to reduce the optical filter drift
by temperature stabilizing.
In which
temperature range is it possible to use
pyroelectric detectors?
InfraTec uses
single crystalline LiTaO3 polished on both
sides as pyroelectric material. This
permanently polarized material has a Curie
temperature of 620° C and therefore does not
limit the usable temperature range. The
maximum operating temperature of the
detector is therefore mainly limited by the
parameters of the integrated preamplifiers.
The mechanical properties of the built-in IR
filters or windows and its assembling
technology limit the minimum and maximum
storage temperature.
Is it possible
to work at operation temperatures over 100°
C?
Principally
this is no problem for the pyroelectric
element itself, however care has to be taken
when selecting the electronic components
like resistor, JFET an OpAmp as these have
to meet the increased specification.
Additionally the built-in IR filter or
window has to be designed for and its
mounting technology must be able to
guarantee a long term hermetical sealing by
buffering mechanical tensions. A combination
of both high (>85°C) and very low
temperatures (<-25°C) is difficult. For
applications with operating temperatures
above 60°C always consider the use of
detectors with CMOS operational amplifiers
instead of JFET because their leakage
current is lower.
What are the
meanings "microphonic effect" or
"acceleration response" as used for pyroelectric detectors?"
All pyroelectric materials are always also
piezoelectric. Therefore the pyroelectric
chip in the detector reacts on impact sound
or airborne sound like a microphone or an
acceleration sensor. This behavior is known
as the microphonic effect or acceleration
response, sometimes also as microphonic
noise. This disturbing effect can be
compensated for very well by an InfraTec
patented pyroelectric chip mounting (so
called low-micro technology).
How does InfraTec
reduce the "microphonic effect"
or "acceleration response" of pyroelectric
detectors and what are the meanings of "low Micro""
or "ultra low microphonic effect" used for pyroelectric detectors from InfraTec?
The airborne
sound can be suppressed by the hermetically
sealed detector housing. The interfering
impact sound can be reduced by an
appropriate mechanical mounting of the pyroelectric chip in that way, that the
physically caused piezoelectric charges will
be compensated. In 2004 InfraTec introduced
new detector families for which a patented micromechanic chip mounting (abbreviation
lowMicro) is reducing the acceleration
response remarkably. These detectors are
characterized as LME (single channel) or LMM
(multi channel) instead of LIE or LIM, where
the second ""M"" stands for Low-Micro.
What is the
purpose of "thermal compensation?"
The DC output
voltage (operating point) of the pyroelectric detector (JFET or OpAmp) can be
stabilized in temperature ramps by about a
factor 20 with the use of a blind,
golden-mirrored antiparallel connected
pyroelectric element. This helps to shorten
the warm up phase or to increase the
accuracy of a handheld IR system. Thermal
compensation is very common for gas
analyzers, less common for flame detection,
not common for spectrometers.
Which
temperature issues cannot be solved by using
"thermal compensation?"
The temperature
compensation does not help to compensate the
temperature drift of the integrated IR
filter. The temperature coefficient (drift)
of the signal voltage and gas concentration
measurement can also not be decreased.
What does
"Voltage mode detector" mean?
In voltage mode
the pyroelectric current charges the
pyroelectric element capacitor, and the
resulting voltage is measured by a source
follower (JFET, gate resistor and external
source resistor). At common modulation
frequencies between 1-10 Hz voltage mode
detectors operate beyond the thermal and
electric time constant in 1/f behavior,
typical signals are a few mV.
What does
"Current mode detector" mean?
In current mode
the pyroelectric current is transformed by a
Current-Voltage-Converter (mainly OpAmp with
feedback components, also called a
Transimpedance-Amplifier TIA). Current mode
detectors normally operate between both
thermal and electrical time constant at
frequencies from 1Hz up to 1 kHz, with
typical signals about 100 mV or more.
Current mode is the more modern operation
mode because there are some advantages.
What are the
main differences of Voltage and Current mode
operation?
For the
detector performance the frequency response
defined by thermal and elecrical time
constant and the resulting signal is of key
importance. The thermal time constant
(typically 150 ms) as a measure of the
thermal coupling of the pyroelectric element
to the environment is effective in both
operation modes. The electrical time
constant in voltage mode is defined as the
product of the pyrochip capacitance and the
gate resistor and can be changed only in a
small range. In current mode it is defined
as the product of feedback resistor and
feedback capacitance. Additionally the
achievable gain of the pyroelectrical signal
in current mode is much higher and can be
adjusted easily by changing the feedback
resistor, while in voltage mode the gain is
only around 0.8. Therefore in current mode
the frequency response and signal voltage of
the detector can be designed much more
individually, which results in possible
operation at high frequencies up to 1kHz
resulting in a very short response time.
How does it
effect the performance of a voltage mode
detector when changing the gate resistor?
The reduction
of the gate resistor in an uncompensated
voltage mode detector is a convenient method
to increase the stability of the Offset
voltage in temperature ramps. It is
therefore often used if a thermal
compensated detector is too expensive.
However, a reduced gate resistor produces an
increased noise proportional to 1/sqrt R.
Rule of thumb: By a thermal compensation the
detectivity of an uncompensated detector
decreases to 70%. For a similar stability an
uncompensated detector has to be designed
with a 1/16 of gate resistor (e.g. 5GOhm
instead of 82GOhm), means the detectivity
decreases to sqrt of 1/16 = 1/4. A thermal
compensation is about 3 times better than
reducing the gate resistor.
How is
it possible to check the functionality of the
detector?
Nearly all
detectors supplied by InfraTec contain a
preamplifier composed of a JFET source
follower or a CMOS-OpAmp. In both
configurations an easy test of the
functionality is to check the DC output
voltage of the detector. In a thermal steady
state and without an IR source the measured
DC output voltage shall agree with the
Offset voltage displayed in the measurement
report supplied together with the detector.
In addition, when heating the detector
carefully with the finger or a hot air
stream a clear changing of the DC output
voltage should arise. Normally, a voltage
mode detector (JFET) shows a DC-shift to the
positive direction, a current mode detector
shows a negative DC-shift.
What are the
advantages of beamsplitter detectors?
In a beamsplitter detector the IR radiation is
entering one aperture window and is divided
internally by a beamsplitter in two or four
parts. Due to the single aperture only a Ø
2.5mm area needs to be illuminated and thus
smaller gas cells with a small gas volume
can be used. Additionally, the signal ratio
of all channels in the detector is stable,
independent from aging, mechanical shift or
pollution because a partial illumination of
the entrance aperture effects all channels
similarly.
What if more
than 4 channels or wavelengths need to be
monitored. Is a second detector necessary?
Normally 3 gas
channels and a reference are monitored with
a 4 channel detector. If you need to monitor
more than 4 channels you have different
options. Often two different 4 channel
detectors are used in parallel using an
external uncoated Si beamsplitter in front
of them. Alternatively, a single channel
detector with a filter wheel having the
number of needed NBP filters for each
spectral channel (up to 8 channels are
common) can be applied. A more sophisticated
possibility is to use InfraTec's Fabry-Perot
detector LFP where a continuous spectrum can
be scanned. Two types of detectors are
available LFP-3041L-337 (tuning range
3..0...4.1µm) and LFP-3950L-337 (tuning
range 3.9...4.8µm)
Is a reference
channel always necessary for a gas analyzing
sensor?
A reference
channel is useful in NDIR gas analyzers to
compensate optical (IR source), mechanical
and electronic long term drifts as well as
drifts by contamination of the optical path.
This reduces the need for re-calibration.
The signal in the gas channel(s) will be
normalized by the reference signal and so
most of the variations will be eliminated.
The spectral position of a reference channel
should be as close as possible to the gas
channel(s) to improve the "normalizing
effect." In many cases one reference
channel can be used for all gas channels of
a multi-gas analyzer. A reference channel is
however not needed if there are other
possibilities to compare the sensor signal
with gas presence and without measuring gas,
for example by changing the gas in the cuvette periodically.
What is the
maximum distance an InfraTec detector can
detect an IR radiation?
This depends on
the detectivity of the detector and
eventually additional optics in front of it.
Distances of up to 100 meters are common in
flame detection. To cover large distances
current mode detectors with large
pyroelectric elements are useful.
Are there
advantages to using a pulsed IR source over
a "chopper"?
A pulsed thermal
IR source is a state-of-the-art solution as
no moving parts in the device construction
are necessary. Please note that electric
pulsing is a modulation of the radiation
power AND the spectral characteristics
according to PLANCK's law. It can however be
used only for modulation frequencies up to a
few ten Hz as the modulation depth of the
thermal source goes down dramatically with
increasing modulation frequency. For larger
frequencies - for example 100 Hz - or for an
exact radiation power modulation a
mechanical chopper is recommended.
What protects
InfraTec devices from moisture and other
contaminants?
All InfraTec
detectors are filled with dried pure
nitrogen and hermitically sealed by welding
the detector cap with the socket. The IR
filter windows are glued with high resistive
and low outgasing epoxy into the cap.
What is the meaning of RoHS (2002/95/EG), WEEE
(2002/96/EG) and REACH (EG 1907/2006)?
RoHS, WEEE and
REACH are three important European
guidelines to protect our environment. RoHS
specifies six banned chemical substances
such as lead, mercury and cadmium. WEEE
(Waste Electrical and Electronic Equipment)
determines how to handle used electric and
electronic devices. REACH appoints to the
interdiction using listed Substances of Very
High Concern in products and production
processes.
Are InfraTec's
pyroelectric detectors and their production
process in accordance with RoHS, WEEE and
REACH?
All device
manufacturers who supply goods inside the
European Union have to assure conformity
with the three EU guidelines RoHS, WEEE and
REACH. It is a part of our Green Policy that
InfraTec as component supplier to certify to
the device manufacturer, that the IR
detectors and their manufacturing process
fulfill all the three EU guidelines.